Recent developments in machine learning and artificial intelligence have enabled the inference of Big 5 personality traits from a single photograph of an individual. This study evaluates the ability of the novel Photo Big 5 personality measure to forecast labor market outcomes. Using the universe of LinkedIn data for MBA graduates, as well as detailed admissions and matriculation records from a top-tier MBA program, we show that the Photo Big 5 is highly predictive of initial compensation. Compared to older survey-based personality measures, the Photo Big 5 is readily available to all employers and less prone to manipulation, and thus has the potential to be widely adopted in firm hiring and promotions processes.